Theoretical modeling on the kinetics of the arsenate-ester hydrolysis: implications to the stability of As-DNA.
نویسندگان
چکیده
Quantum chemical calculations reveal that neither steric hindrance nor less polar solvent medium is able to reduce the otherwise high hydrolysis rate of arsenate-esters. These results question the stability of As-DNA not only in aqueous but also in non-aqueous environments.
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ورودعنوان ژورنال:
- Physical chemistry chemical physics : PCCP
دوره 13 23 شماره
صفحات -
تاریخ انتشار 2011